The table below shows the Lewis Structures for elements with atomic numbers 3 to 10 in the periodic table: The chemical symbol for the element is surrounded by the number of valence electrons present in the ion. The following discussion will not refer to transition metals, lanthanoids (lanthanides) or actinoids (actinides). :6, LiH is highly reactive toward water and other protic reagents::7, LiH is less reactive with water than Li and thus is a much less powerful reducing agent for water, alcohols, and other media containing reducible solutes. National Institute for Occupational Safety and Health, "ChemIDplus - 7580-67-8 - SIAPCJWMELPYOE-UHFFFAOYSA-N - Lithium hydride - Similar structures search, synonyms, formulas, resource links, and other chemical information", Empirical laws for hybrid combustion of lithium hydride with fluorine in small rocket engines, "US 20130083878 A1, April 4, 2013, NUCLEAR REACTORS AND RELATED METHODS AND APPARATUS". For example, silane is produced in the reaction of lithium hydride and silicon tetrachloride by the Sundermeyer process: Lithium hydride is used in the production of a variety of reagents for organic synthesis, such as lithium aluminium hydride (LiAlH4) and lithium borohydride (LiBH4). 1. :157 LiH normally contains some metallic lithium, which corrodes steel or silica containers at elevated temperatures. In order to complete its K shell, hydrogen (Period 1) needs a share in 2 electrons in order to achieve the same electronic configuration as the Noble gas atom helium. Resonance theory or Molecular Orbital (MO) theory give more satisfactory descriptions in this instance. In the Valence Structure for ammonia, the bonding pairs of electrons, which may or may not be circled in the Lewis structure, are replaced by a dash (-) between atoms to represent the covalent bond: Each oxygen atom (Group 16) has 6 valence electrons. :157,182, Some lithium salts, which can be produced in LiH reactions, are toxic. Lithium atom (Group 1, 1 valence electron) loses one electron to form the cation Li, Fluorine atom (Group 17, 7 valence electrons) gains one electron to form the anion F, Lithium fluoride compound is made up of 1 lithium ion and 1 fluoride ion and can be represented as, Each of the two lithium atoms (Group 1, 1 valence electron) loses one electron to form 2 cations Li, Oxygen atom (Group 16, 6 valence electrons) gains two electrons to form the anion O. Lithium oxide compound can be represented as: In a covalent compound, electrons are shared between atoms to form a covalent bond in order that each atom in the compound has a share in the number of electrons required to provide a stable, Noble Gas, electronic configuration. One dot . In the Valence structure for the oxygen molecule, each bonding pair of electrons is replaced by a dash (-) to represent a covalent bond: Each nitrogen atom (Group 15) has 5 valence electrons. Triethylborane reacts to give superhydride (LiBHEt3). The Lewis Structure (electron dot diagram) of each ion is used to construct the Lewis Structure (electron dot diagram) for the ionic compound. Period 2 elements (lithium to fluorine) need a share in 8 electrons to achieve the electron configuration of the Noble Gas (Group 18) element neon. LiH reacts violently with water to give hydrogen gas and LiOH, which is caustic. LiH is not usually a hydride-reducing agent, except in the synthesis of hydrides of certain metalloids. CDC - NIOSH Pocket Guide to Chemical Hazards, Hydrogen chalcogenides (Group 16 hydrides), https://en.wikipedia.org/w/index.php?title=Lithium_hydride&oldid=985124331, Pages with login required references or sources, Pages using collapsible list with both background and text-align in titlestyle, Articles containing unverified chemical infoboxes, Creative Commons Attribution-ShareAlike License, 900–1,000 °C (1,650–1,830 °F; 1,170–1,270 K) (decomposes), extremely strong irritant, highly toxic, highly corrosive, This page was last edited on 24 October 2020, at 02:59. The Lewis structure for this hydrogen ion is [H]+
Peter Rittmeyer, Ulrich Wietelmann "Hydrides" in Ullmann's Encyclopedia of Industrial Chemistry 2002, Wiley-VCH, Weinheim. So, in order for oxygen to complete its octet, the nitrogen atom will provide 2 electrons to share and the oxygen atom will also provide 2 electrons to share: An atom of phosphorus (Period 3, Group 15) has 5 valence electrons: An atom of chlorine (Period 3, Group 17) has 7 valence electrons: Note that the valence shell of Period 1 and Period 2 elements cannot be expanded because d orbitals are not available in the first and second energy levels. Lithium hydride is an inorganic compound with the formula LiH. Many of these formula units make up a crystal lattice. , LiH powder reacts rapidly with air of low humidity, forming LiOH, Li2O and Li2CO3. :9, LiH reacts with acetylene to form lithium carbide and hydrogen. The Lewis structure for the hydride ion is [H:]-For the main group atoms, an atom with many valence electrons (more than 4) will gain enough electrons to form a negative ion that has 8 valence electrons. Screen capture done with Camtasia Studio 4.0. 3. (ii) Atoms of elements with insufficient electrons to share to make up an octet of valence electrons can violate the octet rule. A nitrogen atom requires a share in 3 more electrons to complete its octet of valence electrons. So when we talk about the structure for LiH we think of it together with other LiH formula units in a crystal (NaCl is a good example of this: https://en.wikipedia.org/wiki/Sodium_chloride).Get more chemistry help at http://www.thegeoexchange.org/chemistry/bondingDrawing/writing done in InkScape. This inhibits further reaction, although the appearance of a film of "tarnish" is quite evident. :7 If moist air contains carbon dioxide, then the product is lithium carbonate. Dry oxygen does not react with crystalline LiH unless heated strongly, when an almost explosive combustion occurs. :173–174, 179, Except where otherwise noted, data are given for materials in their, Solvent-and catalyst-free mechanochemical synthesis of alkali metal monohydrides With water-containing acids, LiH reacts faster than with water. Negative ions (anions) are formed when an atom gains electrons. In hydrogen warheads of the Teller–Ulam design, a nuclear fission trigger explodes to heat and compress the lithium-6 deuteride, and to bombard the 6LiD with neutrons to produce 3H (tritium) in an exothermic reaction: 6Li2H + n → 4He + 3H.