SAFETY DATA SHEET Revision Date 14-Feb-2020 Revision Number 3 1. Cautiously neutralize spilled liquid with dilute acid such as dilute sulfuric acid. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 07/06/1998 Revision date: 11/21/2016 Supersedes: 12/29/2015 Version: 2.0 01/26/2018 EN (English US) Page 1 SECTION 1: Identification . ALWAYS stay away from tanks engulfed in fire. 06/26/2013 EN (English) Page 1. .sds-ghs .header, .sds-ghs .content { font-family: 'times_new_roman', 'Times New Roman', sans-serif; } .avoid-page-break-inside { page-break-inside:avoid; } .sds-ghs h1, .sds-ghs h2, .sds-ghs h3, .sds-ghs h4, .sds-ghs h5, .sds-ghs h6 { font-weight: bold; } .sds-ghs h1 { text-align: left; font-size: 2em; margin: 0.67em 0; } .sds-ghs h2 { text-align: left; color: grey; font-size: 1.2em; margin: 0.83em 0; } .sds-ghs h3 { font-size: 1.17em; margin: 10px 0; } .sds-ghs h4 { /*text-align:center;*/ font-size: 1em; margin: 10px 0; } .sds-ghs h5 { font-style: italic; color: grey; font-size: 0.83em; margin: 10px 0; } .sds-ghs p { /*border: 1px solid blue;*/ color: black; line-height: 1; margin-bottom: 5px; } .sds-ghs hr { /*border: 1px solid blue;*/ color: black; margin: 0.5em 0; } .sds-ghs table { width: 100%; border-collapse: collapse; } .sds-ghs table td, .sds-ghs table th { border: 1px solid black; text-align: center; line-height: 1.5em; } .sds-ghs .subtitle { font-size: 12px; color: grey; text-align: right; } .sds-ghs .table-border-none th, .sds-ghs .table-border-none td { border: none; text-align: left; vertical-align: top; line-height: 1; } .sds-ghs .width-pc-70 { width: 70%; } .sds-ghs .width-pc-30 { width: 30%; } .sds-ghs .width-100 { width: 100px; } .sds-ghs .title-number { width: 50px; float: left; display: inline-block; } .sds-ghs .title-content { padding-left: 50px; display: block; } .sds-ghs .title { margin-right: -50px; border-top: 1px solid; } .sds-ghs .content { margin-left: 50px; margin-right: 50px; } .sds-ghs .m-t { margin-top: 15px; } .sds-ghs .text-left { text-align: left; } .sds-ghs h3 { margin-left: -50px; } .sds-ghs h3:before { clear: both; content: ''; }, Hazardous to the aquatic environment, short-term (Acute) - Category Acute 1, H314 Causes severe skin burns and eye damage. LARGE FIRE: Dry chemical, CO2, alcohol-resistant foam or water spray. Liquid. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. 3 Effective date : 11.05.2014 Page 1 of 6 Ammonium Hydroxide, 3M Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - SECTION 1 : Identification of the substance/mixture and of the supplier Product name : Ammonium Hydroxide, 3M Manufacturer/Supplier Trade name: Product Name: Ammonium Hydroxide, ACS Reagent Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]: SMALL FIRE: Dry chemical, CO2 or water spray. Fire may produce irritating, corrosive and/or toxic gases. (ERG, 2016). Avoid formation of dust and aerosols. {�k��Ο�(���(�?�s_���/C�V��0�ਇm�l8a���;�����•|�1�3m����3~N�֙���y����4�?�4�[��JEL�. Do not get water inside containers. The corneal epithelium and endothelium provide a barrier to water soluble substances while the stroma is a barrier to lipid soluble substances. Sweep up and shovel. Fire-fighting measures 5.1 Extinguishing media Suitable extinguishing media. Artificial respiration may be needed. Avoid dust formation. 77, No. Ammonium hydroxide penetrates most rapidly of all alkali compounds. Wash hands before breaks and at the end of workday. Containers may explode when heated. P310 Immediately call a POISON CENTER/doctor/\u2026. Ammonium Hydroxide 1336-21-6 28-30 Water 7732-18-5 Balance 4. Aqueous ammonia and Hg react to form an explosive solid, likely a fulminate. When heated to decomposition it emits ammonia and nitroxides. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. SAFETY DATA SHEET Creation Date 23-Nov-2009 Revision Date 25-Apr-2019 Revision Number 7 1. PRODUCT AND COMPANY IDENTIFICATION Product name: Ammonium Hydroxide ~30% Product code: 05870-16 Supplier: StatLab Medical Products 2090 Commerce Drive McKinney, TX 75069 800-442-3573 972-436-1369 Fax Synonym: None. Rinse skin with water [or shower]. according to Federal Register / Vol. Revision Date: November 1, 2018 Ammonium Hydroxide Page 1 of 9 SAFETY DATA SHEET Section 1. Do NOT induce vomiting. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. : A667-212, A669-212, A669-500, A669P-500; A669-612GAL, A669-385LB, A669C-212, A669S-212, A669S-212EA, A669S-500; NC1020689 Synonyms Ammonia solution; Ammonia water; Ammonium hydrate FIRE INVOLVING TANKS OR CAR/TRAILER LOADS: Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Section 1 - Chemical Product and Company Identification. (ERG, 2016), Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]: Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Isolate from Safety Data Sheet. Do NOT induce vomiting. Continue rinsing. PRODUCT AND COMPANY IDENTIFICATION. Product:)Ammonium)Hydroxide,)50%)v/v) RevisionDate:)05/18/2016) 1/7) Product Identifier: Ammonium Hydroxide, 50% v/v. endobj Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 07/06/1998 Revision date: 06/26/2013 Supersedes: 05/22/2013 Version: 1.2. Contact with molten substance may cause severe burns to skin and eyes. Ammonium Hydroxide, ACS Reagent . Isolate from incompatible substances. See Notes.Keep cool in strong glass, plastic, or rubber stoppered bottles not completely filled. Fresh air, rest. Ammonium Hydroxide, ACS Reagent . Do not discharge to sewer systems. 1.1. Ammonium hydroxide water solution, >/= 14N NH4OH (>/= 25% as ammonia, NH3) ACC# 00211. Ammonium Hydroxide 28-30 1336-21-6 215-647-6 H 5 NO 35.05 g/mol Water Balance 7732-18-5 231-791-2 H 2 O 18.00 g/mol 4. Show this safety data sheet to the doctor in attendance. Move containers from fire area if you can do it without risk. Product Number: 0485 . SAFETY DATA SHEET: AMMONIUM CHLORIDE - AMMONIUM HYDROXIDE BUFFER TS AMMONIUM CHLORIDE - AMMONIUM HYDROXIDE BUFFER TS A631.7A INTEGRA Chemical Company 24 Hour Emergency Response: CHEMTREC 800 … Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Protect against physical damage. Safety Data Sheet . Protect against physical damage. Safety Data Sheet (AQUA AMMONIA 29%) PAGE 4 of 10 7 – HANDLING and STORAGE STORAGE: Keep in a tightly closed container, stored in a cool, dry, ventilated area below 44°C (110°F). Refer for medical attention . Controlled incineration with flue gas scrubbing is possible for combustible packaging materials. Remove contact lenses, if present and easy to do. Recommended Use: For manufacturing, industrial, and laboratory use only. Evacuate personnel to safe areas. Evolves toxic gaseous ammonia with strong bases. Continue rinsing. Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours). 77, No. Ammonium Hydroxide, ACS Safety Data Sheet according to Federal Register / Vol. Calcium hydroxide, sodium hydroxide, and ammonium hydroxide are most often responsible for alkali burns. P301+P330+P331 IF SWALLOWED: Rinse mouth. Keep in a well-ventilated room. P280 Wear protective gloves/protective clothing/eye protection/face protection. Refer for medical attention. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Ventilation. Identification Product Name Ammonium hydroxide Cat No. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. DOT as required by 49 CFR 171.15 and 171.16. X���`I�%&/m�{J�J��t��`$ؐ@������iG#)�*��eVe]f@�흼��{���{���;�N'���?\fdl��J�ɞ!���?~|? J., 1964, 10, 274.). Handle with gloves. Contact time and pH are the most important variables in any chemical burn. Cool containers with flooding quantities of water until well after fire is out. Identification . Details of the supplier of the safety data sheet Keep in suitable, closed containers for disposal. Use personal protective equipment. Wear self-contained breathing apparatus for firefighting if necessary. Show this safety data sheet to the doctor in attendance. : 33285 CAS-No 1336-21-6 Synonyms Ammonia solution; Ammonium hydrate; Ammonia water Recommended Use Laboratory chemicals. Pick up and arrange disposal. << Remove contaminated clothes.